You can follow the below steps to apply for PR in Australia as a skilled worker from Canada:
Step 1: Check if your occupation is on the Skilled Occupation List (MLTSSL or STSOL).
Step 2: Get a skills assessment from the relevant assessing authority for your occupation.
Step 3: Take an English language test (IELTS, PTE, TOEFL, or OET) if required.
Step 4: Submit an Expression of Interest (EOI) via SkillSelect.
Step 5: Achieve at least 65 points on the SkillSelect points test.
Step 6: Wait for an invitation to apply from Home Affairs.
Step 7: Lodge your visa application online, upload documents, and pay the fee.
Step 8: Complete health and character checks.
Step 9: Receive a decision from the Department of Home Affairs.