You can follow the below steps to apply for PR in Australia as a skilled worker from Canada:

Step 1: Check if your occupation is on the Skilled Occupation List (MLTSSL or STSOL).

Step 2: Get a skills assessment from the relevant assessing authority for your occupation.

Step 3: Take an English language test (IELTS, PTE, TOEFL, or OET) if required.

Step 4: Submit an Expression of Interest (EOI) via SkillSelect.

Step 5: Achieve at least 65 points on the SkillSelect points test.

Step 6: Wait for an invitation to apply from Home Affairs.

Step 7: Lodge your visa application online, upload documents, and pay the fee.

Step 8: Complete health and character checks.

Step 9: Receive a decision from the Department of Home Affairs.